Bis(butane-1,4-diammonium) di-μ-oxido-bis[trifluoridooxidomolybdate(V)] monohydrate
نویسندگان
چکیده
The title compound, (C4H14N2)2[Mo2O4F6]·H2O, was obtained by solvothermal reaction at 443 K for 72 h from a mixture of MoO3, HF, 1,4-diamino-butane (dab), water and ethyl-ene glycol. The structure consists of [Mo2O4F6](4-) anionic dimers containing strongly distorted MoO3F3 octa-hedra (with twofold symmetry), diprotonated dab cations and water mol-ecules (twofold symmetry) in the ratio 1:2:1. The cohesion of the three-dimensional structure is ensured through N-H⋯O, N-H⋯F and O-H⋯F inter-actions.
منابع مشابه
Crystal structure of poly[[μ-1,1′-(butane-1,4-diyl)bis(1H-benzimidazole)-κ2 N 3:N 3′]{μ-4,4′-[1,4-phenylenebis(oxy)]dibenzoato-κ4 O,O′:O′′,O′′′}cobalt(II)]
In the title compound, [Co(C20H12O6)(C18H18N4)] n , the Co(II) atom, located on a twofold rotation axis, is hexa-coordinated to four O from two bis-bidentate 4,4'-[phenyl-enebis(-oxy)]dibenzoate (L) ligands and two N atoms from two 1,1'-(butane-1,4-di-yl)bis-(1H-benzimidazole) (bbbm) ligands, forming a distorted octahedral cis-N2O4 coordination environment. Polymeric zigzag chains along [102] a...
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In the title compound, {[CdBr(2)(C(16)H(16)N(2)O(4))]·H(2)O}(n), the Cd(II) ion is six-coordinated by a Br(2)O(4) donor set, with four O atoms from two bridging 1,1'-(butane-1,4-di-yl)bis-(pyridinium-4-carboxyl-ate) ligands. The ligands link the Cd(II) ions into a zigzag chain extending along [0[Formula: see text]1]. O-H⋯O and O-H⋯Br hydrogen bonds involving the uncoordinated water mol-ecules c...
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The butane-1,4-diammonium cation of the title compound, C(4)H(14)N(2) (2+)·2ClO(4) (-), lies on a special position of site symmetry 2/m, whereas the perchlorate anion is located on a crystallographic mirror plane. An intricate three-dimensional hydrogen-bonding network exists in the crystal structure with each H atom of the ammonium group exhibiting bifurcated inter-actions to the perchlorate a...
متن کاملA coordination polymer of CdII with benzene-1,3-dicarboxylate and 1,4-bis[1-(2-pyridylmethyl)benzimidazol-2-yl]butane
The title Cd(II) coordination polymer, catena-poly[[{1,4-bis-[1-(2-pyridylmeth-yl)benzimidazol-2-yl]butane}cadmium(II)]-μ-benzene-1,3-dicarboxyl-ato], [Cd(C(8)H(4)O(4))(C(30)H(28)N(6))](n), was obtained by reaction of CdCO(3), benzene-1,3-dicarboxylic acid (H(2)btc) and 1,4-bis-[1-(2-pyridylmeth-yl)benzimidazol-2-yl]butane (L). The Cd(II) cation is six-coordinated by an N(2)O(4)-donor set. L ac...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012